The term graphene is derived from graphite and the naming suffix of alkenes (ene), indicating an atomic-scale network that the single atomic layer of carbon extended endlessly. That is, a single layer of graphite sheet, which is a two-dimensional carbon material and is a basic unit of various carbon allotropes such as graphene, charcoal, carbon nanotubes, fullerenes, etc. Besides, it is also a general term for single-layer graphene, double-layer graphene, and few-layer graphene. In fact, a single layer or a few layers of carbon atoms (graphene layer) can be called graphene. Graphene is currently the thinnest material artificially produced in the world, with a thickness of a single carbon atom only 0.335 nm.
Perfect graphene has an ideal two-dimensional crystal structure composed of hexagonal lattices. Each carbon atom is connected to three other carbon atoms through a strong σ covalent bond, forming a strong C-C bond. Moreover, each carbon atom contributes a non-boding л electron, and these л electrons form a л orbital perpendicular to the plane. These л electrons can move freely in the crystal, endowing graphene with excellent mechanical strength and conductivity. Therefore, graphene is a two-dimensional carbon nanomaterial consisting of carbon atoms in a hexagonal honeycomb lattice with sp2 hybrid orbitals.
Graphene materials refer to graphene-related two-dimensional carbon materials with no more than 10 carbon atom layers, including single-layer graphene, double-layer graphene, few-layer graphene, graphene, single-layer graphene oxide, graphene oxide, single-layer reduced graphene oxide, reduced graphene, and functionalized graphene.
Graphene and graphene-related materials are widely used in battery electrode materials, semiconductor devices, transparent displays, sensors, capacitors, transistors, etc. Given the excellent properties of graphene materials and their potential applications, a series of significant advances have been made in a wide range of disciplines, including chemistry, materials science, physics, biology, environmental science and energy.