
Natural flake graphite is a kind of crystalline graphite with a fish scale like appearance and presents a layered structure.

Graphite is a crystalline form of carbon that is black to dark gray, soft and slippery. It has a distinct layered structure, with a single layer of carbon atoms bonded to three other carbon atoms through covalent bonds to form a covalent molecule. It was named by Abraham Gottlob Werner in 1789 and originated from the Greek word γράφειν. It is an allotrope of carbon.
Natural graphite is a carbonaceous crystalline mineral that is generally found in ores such as graphite schist, graphite gneiss, graphite-bearing schist, and metamorphic shale. It has two common forms: crystalline (flake graphite) and cryptocrystalline (amorphous graphite).
In addition, there is another type of graphite called vein (crystalline vein) graphite. There is some controversy about its origin, suspecting that it is a result of pyrolysis of graphite naturally occurred. In simple terms, solid graphite carbon may be deposited from a high-temperature fluid as it flows. Once the fluid cools, this graphite carbon forms graphite flows or veins in the surrounding rock. Carbon-rich gases may react with the high-temperature fluid to form deposited graphite solids, or may be absorbed as the fluid flows. It typically appears as fibrous or needle-like crystalline aggregate.
The graphite structure is intermediate between atomic crystals, metallic crystals, and molecular crystals, and has a unique crystal structure, so it has some special properties.